Documentation Revision Date: 2021-09-20
Dataset Version: 1
Summary
Observations in Fairbanks, Alaska, began in August to October 2016 using two single detectors EM27/SUN FTS, owned by LANL and KIT. In 2017, continuous observations were collected during March through October at UAF using the LANL EM27/SUN with a single detector. In 2018–2019, continuous observations were collected from April to October at UAF using the EM27/SUN owned and maintained by KIT as a part of the Collaborative Carbon Column Observing Network. In May–June 2018, three FTS instruments, including the KIT EM27 at UAF, the LANL EM27 with an upgrade to include a dual detector, and an EM27/SUN FTS owned by Caltech and the Jet Propulsion Laboratory (JPL) with a single detector were deployed.
There are five data files in comma-separated text (*.csv) format.
Citation
Jacobs, N., W.R. Simpson, F. Hase, T. Blumenstock, Q. Tu, M. Frey, M.K. Dubey, and H.A. Parker. 2021. Ground-based Observations of XCO2, XCH4, and XCO, Fairbanks, AK, 2016-2019. ORNL DAAC, Oak Ridge, Tennessee, USA. https://doi.org/10.3334/ORNLDAAC/1831
Table of Contents
- Dataset Overview
- Data Characteristics
- Application and Derivation
- Quality Assessment
- Data Acquisition, Materials, and Methods
- Data Access
- References
Dataset Overview
This dataset provides ground-based column-averaged dry mole fractions (DMFs) of CO2 (xco2), CO (xco), CH4 (xch4), and N2O (xn2o) to supplement satellite-based observations of carbon dynamics of northern boreal ecosystems. Measurements were conducted with Bruker EM27/SUN Fourier transform spectrometers (FTS) at the University of Alaska Fairbanks (UAF) and two sites on the edges of the Tanana Flats wetlands to the south from 2016-08-04 to 2019-10-31. Single detectors were used during the first campaign at UAF in 2017, then two instruments were updated to dual detectors in early 2018 to allow retrieval of xco and xn2o. Data from additional FTS instruments, operated by Los Alamos National Laboratories (LANL), Karlsruhe Institute of Technology (KIT), and Jet Propulsion Laboratory (JPL), employed in these campaigns are included.
Observations in Fairbanks, Alaska, began in August to October 2016 using two single detectors EM27/SUN FTS, owned by LANL and KIT. In 2017, continuous observations were collected during March through October at UAF using the LANL EM27/SUN with a single detector. In 2018–2019, continuous observations were collected from April to October at UAF using the EM27/SUN owned and maintained by KIT as a part of the Collaborative Carbon Column Observing Network. In May–June 2018, three FTS instruments, including the KIT EM27 at UAF, the LANL EM27 with an upgrade to include a dual detector, and an EM27/SUN FTS owned by Caltech and the Jet Propulsion Laboratory (JPL) with a single detector were deployed.
Related Publication
Jacobs, N., W.R. Simpson, D. Wunch, C.W. O’Dell, G.B. Osterman, F. Hase, T. Blumenstock, Q. Tu, M. Frey, M.K. Dubey, H.A. Parker, R. Kivi, and P. Heikkinen. 2020. Quality controls, bias, and seasonality of CO2 columns in the boreal forest with Orbiting Carbon Observatory-2, Total Carbon Column Observing Network, and EM27/SUN measurements. Atmospheric Measurement Techniques 13:5033–5063. https://doi.org/10.5194/amt-13-5033-2020
Acknowledgments
This research was funded by the NASA OCO Science Team (grant NNH17ZDA001N-OCO2).
Data Characteristics
Spatial Coverage: Fairbanks areas, Alaska, USA
Spatial Resolution: Multiple points
Temporal Coverage: 2016-08-04 to 2019-10-31
Temporal Resolution: 15 seconds, variable
Study Area: Latitude and longitude are given in decimal degrees.
Sites | Westernmost Longitude | Easternmost Longitude | Northernmost Latitude | Southernmost Latitude |
---|---|---|---|---|
Fairbanks, Alaska, and surrounding area | -149.09 | -147.859 | 65.118 | 64.859 |
Data File Information
There are five data files in comma-separated text (*.csv) format included in this dataset. The files are named <owner>_<instrument>_<dates>.csv, where
<owner> = the instrument owner, Los Alamos National Laboratories (lanl), Karlsruhe Institute of Technology (kit), and Jet Propulsion Laboratory (jpl)
<instrument> = single or dual instruments deployed
<dates> = year (YYYY) and month (MM) of data collection; multiple dates may be included in the file name
Table 1. File names and descriptions.
File Name | Description |
---|---|
kit_single_201608_201610.csv | Column-averaged dry mole fractions of CO2 (xco2) and CH4 (xch4) collected at Fairbanks and on the edges of the Tanana Flats wetlands to the south, starting in August 2016 using the Bruker EM27/SUN FTS. In this dataset, xco2 and xch4 were retrieved using GGG2014 coupled with the EM27/SUN GGG interferogram processing suite. |
kit_dual_201804_201910.csv | Column-averaged dry mole fractions of CO2 (xco2), CH4 (xch4), and CO (xco) collected April 2018 to October 2019 at Fairbanks with an upgrade to include a dual detector for retrieving xco. |
lanl_single_201608-201610_201703-201711.csv | Column-averaged dry mole fractions of CO2 (xco2) and CH4 (xch4) collected August to October 2016 at Fairbanks using two EM27/SUN FTS, owned by LANL and KIT, each with a single detector for retrieving xco2 and xch4. |
lanl_dual_201805-201806.csv | Column-averaged dry mole fractions of CO2 (xco2), CO (xch4), and CH4 (xco) collected at Fairbanks during May and June 2018 using the EM27/SUN FTS, including the KIT EM27 at Fairbanks, and the LANL EM27 with an upgrade to include a dual detector. |
jpl_single_201805-201806.csv | Column-averaged dry mole fractions of CO2 (xco2) and CH4 (xch4) collected May to June 2018 using an EM27/SUN FTS owned by Caltech and JPL with a single detector for retrieving xco2 and xch4. |
Table 2. Variables in the data files. Note: N2O, H2O, and HDO are provided but are not the primary data products and have undergone only very limited vetting to verify their precision and accuracy.
Variable | Units | Description |
---|---|---|
spectrum | Spectrum | |
date | YYYY-MM-DD | Date of observation |
year | YYYY | Year of observation |
day | DDD | Day of year of observation |
hour | Fractional UT Hour | |
latitude | Decimal degrees | Latitude |
longitude | Decimal degrees | Longitude |
zobs | km | Geometric altitude |
zmin | km | Pressure altitude |
asza | degrees | Solar Zenith Angle |
azim | degrees | Solar Azimuth Angle |
osds | ppm | Observer-Sun Doppler Stretch |
opd | cm | Optical path difference |
fovi | rad | Internal Field of View |
graw | cm-1 | Spectral Point Spacing |
internal_temp | Degrees C | Internal temperature |
internal_pressure | mbar | Internal pressure |
external_temp | C | External temperature |
external_pressure | hPa | External pressure |
external_humidity | % | External humidity |
sia | AU | Solar Intensity (Average) was -2.0 9999 |
fvsi | % | Fractional Variation in Solar Intensity |
xair | ppm | Calculated as: 0.2095*Column air/column dry air |
xair_error | ppm | One-sigma precision |
xh2o | ppm | Column_h2o/column dry air |
xh2o_error | ppm | One-sigma precision |
xhdo | ppm | Calculated as: 0.2095*Column_h2o/column dry air |
xhdo_error | ppm | One-sigma precision |
xco | ppb | Calculated as: 0.2095*Column hdo/column dry air (not provided in single detector files) |
xco_error | ppb | One-sigma precision |
xn2o | ppb | Calculated as: 0.2095*Column co/column dry air |
xn2o_error | ppb | One-sigma precision |
xch4 | ppm | Calculated as: 0.2095*Column ch4/column dry air |
xch4_error | ppm | One-sigma precision |
xco2 | ppm | Calculated as: 0.2095*Column co2/column dry air |
xco2_error | ppm | One-sigma precision |
Table 3. Air mass correction factors.
Retrieved Gas | Airmass-Dependent Correction Factors |
xco2 | -0.0068 0.0050 |
xch4 | 0.0053 0.0080 |
xn2o | 0.0039 0.0100 |
xco | -0.0483 0.1000 |
xh2o | -0.0000 0.0000 |
Retrieved Gas | Airmass-Independent/In-Situ Correction Factors |
xco2 | 0.9898 0.0010 |
xch4 | 0.9765 0.0020 |
xn2o | 0.9638 0.0100 |
xco | 1.0672 0.0200 |
xh2o | 1.0183 0.0100 |
Application and Derivation
Regional-scale observations of atmospheric CO2, CH4, and CO are necessary for closing gaps in the carbon budget across the ABoVE domain and on continental and global scales. Ground-based column-averaged dry air mole fractions of these greenhouse gases complement aircraft and tall tower observations, and they can be used for satellite and model validation (Jacobs et al., 2020).
Quality Assessment
The dry column-average CO2 DMF (column CO2/column O2) can be affected by three main sources of error.
- Measurement precision: The standard deviation of column CO2/column O2 during a one-hour period was <0.1% under clear sky conditions and approximately 0.2% under partly cloudy conditions. The repeatability of the measurement was not a significant source of error.
- Spectroscopic errors: The absolute accuracy of the CO2, CH4, and CO retrievals were calibrated by comparison to integrated aircraft profiles resulting in the previously reported Airmass-Independent Correction Factors. The standard deviation of the fitting residuals was approximately 0.1%. The aircraft profiles were performed with the sun at air mass 1.1 to 2.0 (SZA 25 to 60 degrees) and the column-averaged CO2 DMF was calibrated for these values. However, additional systematic errors may be present at higher air masses due to errors in spectroscopy.
- Systematic instrumental changes over time: These were mitigated by calibrations and instrument maintenance performed by Frank Hase and colleagues at the Karlsruhe Institute of Technology (KIT) every one to two years.
Refer to Jacobs et al. (2020) for details.
Data Acquisition, Materials, and Methods
Ground-based measurements of column-averaged dry mole fractions (DMF) of CO2 (xco2), CO (xco), CH4 (xch4), and N2O (xn2o) were collected in the vicinity of Fairbanks, Alaska, USA. Measurement sites included the University of Alaska Fairbanks (UAF) and on the edges of the Tanana Flats wetlands south of UAF using Bruker EM27/SUN Fourier transform spectrometers (FTS),
- In August–October 2016, observations in Fairbanks began using two EM27/SUN FTS, owned by Los Alamos National Laboratories (LANL) and Karlsruhe Institute of Technology (KIT), each with a single detector for retrieving xco2 and xch4.
- In March - October 2017, continuous observations were collected at UAF using the LANL EM27/SUN with a single detector.
- In 2018 and 2019, continuous observations were collected during April through October at UAF using the EM27/SUN owned by KIT as a part of the Collaborative Carbon Column Observing Network (COCCON; https://www.imk-asf.kit.edu/english/COCCON.php).
- In May–June 2018, three EM27/SUN FTS, including the KIT EM27 at UAF, the LANL EM27, and an EM27/SUN FTS owned by the Jet Propulsion Laboratory (JPL) with a single detector were deployed.
The Bruker EM27/SUN FTS was developed by KIT in collaboration with Bruker Optics (Gisi et al., 2012; Hase et al., 2016) to be a compact, mobile solar-viewing FTS designed for field deployment and has a resolution of 0.5 cm−1. Columns of gases were retrieved for multiple bands or micro-windows and the average of those individual band retrievals were calculated to obtain the dry mole fractions (DMF) of CO2, CO, CH4, and N2O.
Regular characterization of the Instrument Line Shape (ILS) for each EM27/SUN spectrometer was used to monitor instrument performance over time. Retrieval methods for EM27/SUN retrievals of xco2 were used by implementing the GGG2014 retrieval algorithm (Wunch et al., 2015) coupled with the EM27/SUN GGG interferogram processing suite (EGI) (Hedelius and Wennberg, 2017). N2O, H2O, and HDO are included in this dataset but are not the primary data products; these measurements have undergone only very limited vetting to verify their precision and accuracy.
Quality controls applied to EM27/SUN retrievals follow those outlined by Hedelius et al. (2016) including an upper bound on sun zenith angle (sza) at 82 degrees and an upper bound on CO2 retrieval error at 5 ppm. In addition, a lower bound is set on the average solar intensity (sia) in EM27/SUN retrievals at 90 AU.
Refer to Jacobs et al. (2020) for details.
Data Access
These data are available through the Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC).
Ground-based Observations of XCO2, XCH4, and XCO, Fairbanks, AK, 2016-2019
Contact for Data Center Access Information:
- E-mail: uso@daac.ornl.gov
- Telephone: +1 (865) 241-3952
References
Frey, M., M.K. Sha, F. Hase, M. Kiel, T. Blumenstock, R. Harig, G. Surawicz, N.M. Deutscher, K. Shiomi, J.E. Franklin, H. Bösch, J. Chen, M. Grutter, H. Ohyama, Y. Sun, A. Butz, G. Mengistu Tsidu, D. Ene, D. Wunch, Z. Cao, O. Garcia, M. Ramonet, F. Vogel, and J. Orphal. 2019. Building the COllaborative Carbon Column Observing Network (COCCON): long-term stability and ensemble performance of the EM27/SUN Fourier transform spectrometer. Atmospheric Measurement Techniques 12:1513–1530. https://doi.org/10.5194/amt-12-1513-2019
Gisi, M., F. Hase, S. Dohe, T. Blumenstock, A. Simon, and A. Keens. 2012. XCO2-measurements with a tabletop FTS using solar absorption spectroscopy. Atmospheric Measurement Techniques 5:2969–2980. https://doi.org/10.5194/amt-5-2969-2012
Hase, F., M. Frey, M. Kiel, T. Blumenstock, R. Harig, A. Keens, and J. Orphal. 2016. Addition of a channel for XCO observations to a portable FTIR spectrometer for greenhouse gas measurements. Atmospheric Measurement Techniques 9:2303–2313. https://doi.org/10.5194/amt-9-2303-2016
Hedelius, J., and P. Wennberg. 2017. EM27/SUN GGG interferogram processing suite. CaltechDATA. https://doi.org/10.22002/d1.306
Jacobs, N., W.R. Simpson, D. Wunch, C.W. O’Dell, G.B. Osterman, F. Hase, T. Blumenstock, Q. Tu, M. Frey, M.K. Dubey, H.A. Parker, R. Kivi, and P. Heikkinen. 2020. Quality controls, bias, and seasonality of CO2; columns in the boreal forest with Orbiting Carbon Observatory-2, Total Carbon Column Observing Network, and EM27/SUN measurements. Atmospheric Measurement Techniques 13:5033–5063. https://doi.org/10.5194/amt-13-5033-2020
Wunch, D., J. Mendonca, O. Colebatch, N.T. Allen, J.-F. Blavier, S. Springett, G. Neufeld, K. Strong, R. Kessler, and D. Worthy. 2017, March 28. TCCON data from East Trout Lake, SK (CA), Release GGG2014.R0. CaltechDATA. https://doi.org/10.14291/tccon.ggg2014.easttroutlake01.R0/1348207
Wunch, D., G.C. Toon, V. Sherlock, N.M. Deutscher, C. Liu, D.G. Feist, and P.O. Wennberg. 2015. Documentation for the 2014 TCCON Data Release. CaltechDATA. https://doi.org/10.14291/tccon.ggg2014.documentation.R0/1221662
Wunch, D., G.C. Toon, J.-F.L. Blavier, R.A. Washenfelder, J. Notholt, B.J. Connor, D.W. T. Griffith, V. Sherlock, and P.O. Wennberg. 2011. The Total Carbon Column Observing Network. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 369:2087–2112. https://doi.org/10.1098/rsta.2010.0240